An optically active monomer containing azobenzene moieties with chiral group (s-2-methyl-butyl), 4-[2-(methacryloyloxy)ethyloxy]-4’-(s-2-methyl-1-butyloxycarbonyl) azobenzene(Ml) was synthesized. Polymer (PMl)possessing optical phase conjugated response was obtained by homopolymerzation of the optically active monomer (Ml)using free radical polymerization. The polymer was very soluble in common solvents and good optical quality films could beeasily fabricated by spin coating. The optical phase conjugated responses of the polymer PM1 were measured by degeneratefour-wave mixing (DFWM). In comparison with polymer containing no chiral group, it was found from the preliminarymeasurement of photoisomeric change that optical phase conjugated response of the PM1 in the long-range order hexagonalsymmetry microstructure could be easily controlled by choosing the appropriate polarization direction of the irradiatingbeams (514.5 nm) and the irradiating number, presumably due to the chiral group in the PM1 molecular structure. For thecase of the polymer investigated here, a chiral group side chain was introduced to increase optical phase conjugated responseintensity with different polarization directions of the irradiating beams, which aims originally at searching for a new photo-ative material. An optically active monomer containing azobenzene moieties with a chiral group (s-2-methyl-butyl), 4- [2- (methacryloyloxy) ethyloxy] -4’- synthesized. Polymer (PMl) possessing optical phase conjugated response was obtained by homopolymerzation of the optically active monomer (Ml) using free radical polymerization. The polymer was very soluble in common solders and good optical quality films could beeasily fabricated by spin coating. The optical phase conjugated responses of the polymer PM1 were measured by degeneratefour-wave mixing (DFWM). In contrast with the polymer containing no chiral group, it was found from the preliminary measurement of photoisomeric change that optical phase conjugated response of the PM1 in the long-range order hexagonalsymmetry microstructure could be easily controlled by choosing the appropriate polarization direction of the irradiating beads (514.5 nm) and the irradiating number, presumably due to the chiral group in the PM1 molecular structure. For the case of the polymer investigated here, a chiral group side chain was introduced to increase optical phase conjugated response intensity with different polarization directions of the irradiating beams, the aims originally at searching for a new photo-ative material.