This study covers the transportation of Cu(Ⅱ) ions by multi-dropped liquid membrane(MDLM) system and tri-noctylamine(TNOA) as carrier in kerosene. Batch experiments are held to obtain optimum conditions for the transportation of Cu(Ⅱ) ions such as volume of donor, organic, and acceptor phase 100 ml, p H of donor phase9.00, temperature 298.15 K, concentration of H_2SO_4 in acceptor phase 1.00 mol·L~(-1), concentration of TNOA in organic phase 5.00 × 10~(-3)mol·L~(-1)and rate of peristaltic pump 50 ml·min~(-1). Optimum circumstances of this extraction are as follows: p H of donor phase is 9.00, concentration of TNOA is 5.00 × 10~(-3)mol·L~(-1),1.00 mol·L~(-1)H_2SO_4 as acceptor phase, and flux rate is 50 ml·min~(-1). Cu(Ⅱ) ion transportation is consecutive first order irreversible reaction. Activation energy is found as 5.22 kcal·mol-1(21.82 k J·mol~(-1), this process is called as diffusion controlled system. Selective transportation of Cu(Ⅱ) ions with alkaline, alkaline earth, and different heavy metal ions at optimum conditions of single Cu(Ⅱ) extraction was conducted. According to the selective transportation Cu(Ⅱ) ions with alkaline and alkaline earth metal ions, Na~+, K~+, and Ba~(2+)ions are not detected in the acceptor phase, but 12.00% of Ca~(2+)ions is transported from donor phase to acceptor phase. At the end of the simultaneous extraction of Zn(Ⅱ), Fe(ⅡI), and Mo(VI) with Cu(Ⅱ) ions, 2.20% of Mo(VI), 0.80% of Fe(Ⅲ) and 3.60% of Zn(Ⅱ) are detected in the acceptor phase. This study covers the transportation of Cu (II) ions by multi-dropped liquid membrane (MDLM) system and tri-noctylamine (TNOA) as carrier in kerosene. Batch experiments are held to obtain optimum conditions for the transportation of Cu (II) ions such as volume of donor, organic, and acceptor phase 100 ml, p H of donor phase 9.00, temperature 298.15 K, concentration of H 2 SO 4 in acceptor phase 1.00 mol·L -1, concentration of TNOA in organic phase 5.00 × 10 -3 mol·L -1 and rate of peristaltic pump 50 ml · min -1. Optimum conditions of this extraction are as follows: p H of donor phase is 9.00, concentration of TNOA is 5.00 × 10 ~ (-3) mol·L -1, 1.00 mol·L -1 H_2SO_4 as acceptor phase, and the flux rate is 50 ml · min -1. This process is called as diffusion controlled system. Selective transportation of Cu (Ⅱ) ions with alkaline (alkaline earth metal) was found to be 5.22 kcal · mol-1 (21.82 kJ · mol -1) , alkalin e earth, and different heavy metal ions at optimum conditions of single Cu (Ⅱ) extraction was conducted. According to the selective transportation of Cu (Ⅱ) ions with alkaline and alkaline earth metal ions, Na ~ +, K ~ (2+) ions are not detected in the acceptor phase, but 12.00% of Ca ~ (2+) ions are transported from the donor phase to acceptor phase. At the end of the simultaneous extraction of Zn (II), Fe , and Mo (VI) with Cu (II) ions, 2.20% of Mo (VI), 0.80% of Fe (III) and 3.60% of Zn (II) are detected in the acceptor phase.