报道了一系列铜与含氮、氧、磷配体形成的配位催化剂用于甲醇氧化羰化合成碳酸二甲酯的研究结果。在１２０℃～１３０℃、３．０ ＭＰａ的反应条件下，氯化亚铜／联吡啶配位催化剂具有最好的活性、选择性和稳定性。在实际反应条件下的挂片试验结果表明，氯化亚铜／联吡啶催化剂对一种特种不锈钢材料的腐蚀速率为０．０２４毫米／年。 Reported a series of copper and nitrogen, oxygen, phosphorus ligands form a coordination catalyst for the methanol oxidative carbonylation of dimethyl carbonate research results. Under the reaction conditions of 120 ℃ ~ 130 ℃ and 3.0 MPa, cuprous chloride / bipyridine coordination catalyst has the best activity, selectivity and stability. The coupon test results under the actual reaction conditions show that the corrosion rate of cuprous chloride / bipyridine catalyst to a special stainless steel material is 0.024 mm / year.