Structure and Magnetic Properties of S-doped Mn_3O_4/S Composited Nanoparticles and Mn_3O_4 Nanopart

来源 :Journal of Materials Science & Technology | 被引量 : 0次 | 上传用户:ylovew
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Composited nanoparticles,consisting of Mn3O4,S-doped Mn3O4 and S,were synthesized by co-precipitation reaction and Mn3O4 nanoparticles were then obtained after removing the pure S from the composited nanoparticles.The Mn3O4-type phase with larger lattice constant a was formed by doping sulfur.At fixed temperatures below Curie temperature(TC),the magnetization of the S-doped Mn3O4/S composited nanoparticles was smaller than that of the Mn3O4 nanoparticles.The blocking temperature was 36.3 and 34.8 K for Sdoped Mn3O4/S composite and Mn3O4 nanoparticles,respectively.The anisotropy field of S-doped Mn3O4/S composite was determined to be about 55.3 kOe. Composited nanoparticles, consisting of Mn3O4, S-doped Mn3O4 and S, were synthesized by co-precipitation reaction and Mn3O4 nanoparticles were then obtained after removing the pure S from the composited nanoparticles. The Mn3O4-type phase with larger lattice constant was formed by doping sulfur. At fixed temperatures below Curie temperature (TC), the magnetization of the S-doped Mn3O4 / S composited nanoparticles was smaller than that of the Mn3O4 nanoparticles. The blocking temperature was 36.3 and 34.8 K for Sdoped Mn3O4 / S composite and Mn3O4 nanoparticles, respectively. The anisotropy field of S-doped Mn3O4 / S composite was determined to be about 55.3 kOe.
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