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对化合物[Cu(O-2,2’-bipy)]8[PW12O40{Cu(4,4’-bipy)2}2]·OH进行了元素分析、红外光谱、X-射线光电子能谱等测试。结果表明:元素分析与化合物的化学式相符;红外光谱出现N-H的伸缩振动峰、N-H、C-H弯曲振动峰、P-O的伸缩振动峰、W-Ob-W的反对称伸缩振动峰及W=O伸缩振动吸收峰为强吸收峰;光电子能谱出现36.9 eV的W6+4f7/2的电子结合能。
The elemental analysis, infrared spectroscopy, X-ray photoelectron spectroscopy and other tests were performed on the compound [Cu (O-2,2’-bipy)] 8 [PW12O40 {Cu (4,4’-bipy) 2} . The results showed that the elemental analysis was in accordance with the chemical formula of the compound. The infrared spectrum showed NH stretching vibration peak, NH, CH bending vibration peak, PO stretching vibration peak, W-Ob-W antisymmetric stretching vibration peak and W = O stretching vibration The absorption peak is a strong absorption peak; the electron binding energy of 36.9 eV W6 + 4f7 / 2 appears in the photoelectron spectrum.