Investigation on the electrochemical behaviours of Mg2-xCrxNi negative electrode

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A series of Mg2-xCrxNi alloy powder has been produced by combination of solid-state diffusion with mechanicalgrinding (MG). X-ray diffraction patterns show that the alloy powders have an amorphous structure and great increase in thespecific surface. Electrochemical detection results indicate that the partial substitution of Mg by Cr in Mg2Ni alloy improvesthe cycle life of this alloy greatly, which gets up to 100 cycles at 200 mA/g mass discharge current, keeping its mass dis-charge capacity over 200 mA@h/g. In the meanwhile, partial replacement of Mg by Cr also increases the mass discharge ca-pacity compared with Mg2Ni alloy. With the increasing of mass discharge current and content of Cr in Mg2-xCrxNi, the cyclelife of the alloys are increased and the decay of mass discharge capacity slows down.
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