【摘 要】
：
Compound [V16O38(Cl)][Cu(enMe)2]3.5*2H2O(1) has been hydrothermally synthesized and characterized by means of single-crystal X-ray diffraction, elemental analys
【机 构】
：
Coordination and Hydrothermal Chemistry Group,State Key Laboratory of Coordination Chemistry
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Compound [V16O38(Cl)][Cu(enMe)2]3.5*2H2O(1) has been hydrothermally synthesized and characterized by means of single-crystal X-ray diffraction, elemental analysis, IR, EPR and TGA analysis. The X-ray crystallography shows that compound 1 contains a new {V16O38} cluster shell, which is connected by [Cu(enMe)2]2+ coordination fragments into a 3-D framework. The compound crystallized in a monoclinic system with space group P2(1)/n, M=2235.82, a=1.26076(3) nm, b=2.55802(6) nm, c=2.14742(4) nm, β=90.7380(10)°, V=6.9250(3) nm3, Z=4, F(000)=4418, Dc=2.145 g*cm-3, μ=3.227 mm-1,(Δ/σ)=0.000, S=1.066.
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