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Ｋｅｌｅｔ等［１］研究ＣｏＴＭＡＰＩ催化水制取氢气的反应时指出，活性中心是一价钴卟啉．曹锡章等［２］研究钴卟啉催化ＣＯ２电化学还原时指出，活性中心也是一价钴卟啉．然而，不稳定价态的金属卟啉配合物的制备和性质研究较为困难．光谱电化学的迅速发展为不稳定价...
Kelet et al [1] study CoTMAPI catalytic hydrogenation of water to the reaction that the active center is a monovalent cobalt porphyrin. Cao Xizhang et al [2] study of cobalt porphyrin catalyzed electrochemical reduction of CO2 pointed out that the active center is also a price of cobalt porphyrin. However, the preparation and properties of unstable valence metalloporphyrins have been difficult to study. The rapid development of spectrochemical electrochemical instability price ...