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The synthesis of dimethyl carbonate (C_3H_6O_3) by the reactions of methanol carbonylation over carbon-supported palladium catalysts at atmospheric pressure is studied in this letter. Therein methyl nitrite (CH_3ONO) was introduced as a cyclic reagent in the heterogenous catalytic reactions. Since ~+NO in methyl nitrite shows
The synthesis of dimethyl carbonate (C_3H_6O_3) by the reactions of methanol carbonylation over carbon-supported palladium catalysts at atmospheric pressure is studied in this letter. Therein methyl nitrite (CH_3ONO) was introduced as a cyclic reagent in the heterogenous catalytic reactions. NO in methyl nitrite shows