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通过溶胶 凝胶法和O/W型乳液聚合法制备了经过十二烷基苯磺酸钠 (SDBS)修饰的纳米ZnO粉体和纳米ZnO/聚苯胺 (PAn)的复合材料 ,并进行了形貌、结构和性质的表征与分析。结果表明 ,纳米氧化锌晶形为六方晶系球形结构 ,粒径平均为 2 5nm。而纳米ZnO/PAn的复合材料也呈现出特殊的红外吸收特性 ,在 170 0cm- 1~ 330 0cm- 1出现 1个较强的吸收峰 ,同时因纳米ZnO的加入而使聚苯胺各特征峰振动强度均增强 ,所以可得出 ,纳米ZnO的掺杂对聚苯胺的红外光谱的影响较大
The composite materials of nanometer ZnO / polyaniline (PAn) modified by sodium dodecyl benzene sulfonate (SDBS) were prepared by sol-gel method and O / W emulsion polymerization. Appearance, structure and nature of the characterization and analysis. The results show that the crystal form of hexagonal ZnO nanocrystalline spherical structure, an average particle size of 25nm. The nano-ZnO / PAn composite also showed a special infrared absorption characteristics, a strong absorption peak appeared at 170 0cm -1 ~ 330 0cm -1, and the polyaniline vibration peaks The intensity is enhanced, it can be drawn, the doping of nano-ZnO polyaniline infrared spectrum greater impact