【摘 要】
:
A novel compound, (E)-4’-(4-(but-1-en-3-ynyl)phenyl)-2,2’:6’,2’’-terpyridine 1 was synthesized from 4’-(4-bromomethylphe- nyl)-2,2’:6’,2’’-terpyridine
【出 处】
:
Chinese Chemical Letters
论文部分内容阅读
A novel compound, (E)-4’-(4-(but-1-en-3-ynyl)phenyl)-2,2’:6’,2’’-terpyridine 1 was synthesized from 4’-(4-bromomethylphe- nyl)-2,2’:6’,2’’-terpyridine phosphonium salt 2 and propargylaldehyde via Wittig reaction, and characterized by EI-MS and 1H NMR as well as elemental analysis. The spectral changes of the compound in the presence of transition metal ions, such as Cu(Ⅰ) or Zn(Ⅱ), are investigated.
A novel compound, (E) -4 ’- (4- (but-1 -en-3 -ynyl) phenyl) -2,2’: 6 ’ -bromomethylpheranyl) -2,2 ’: 6’, 2 "- terpyridine phosphonium salt 2 and propargylaldehyde via Wittig reaction, and characterized by EI-MS and 1H NMR as well as elemental analysis. The spectral changes of the compound in the presence of transition metal ions, such as Cu (I) or Zn (II), are investigated.
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