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The reaction of Co~II ions with 1,4-bis(imidazol)butane(bimb) or 1,4-bis(triazol)butane(bitb) in the presence of ClO_4~-, respectively affords two CoII coordination complexes, namely {[Co(bimb)_3]·2ClO_4}n(I) and {[Co(bitb)_3]·2ClO_4}n(II). Sing