为了提高产率 ,以 5,6-二胺-1,10-邻菲咯啉与 1,10-邻菲咯啉-5,6-二酮反应 ,合成了配体四吡啶 [3,2-a:2′ ,3′-c:3″ ,2″-h:2“’ ,3”’-j]吩嗪（ tpphz）。以此配体为桥合成了钴(III)、镍 (II)为中心金属的三种新的双核配合物。用元素分析、红外光谱、质子核磁共振、热重分析、中心金属滴定等手段对配合物进行了结构表征 ,并研究了其紫外和荧光光谱性质。 In order to improve the yield, the ligand tetrapyrido [3,2-d] pyrimidine was synthesized by the reaction of 5,6-diamine-1,10-phenanthroline and 1,10-phenanthroline- a: 2 ’, 3’-c: 3 “, 2” -h: 2 “’, 3 ’” - j] phenazine (tpphz). Using this ligand as a bridge, three new binuclear complexes of cobalt (III) and nickel (II) as the central metal were synthesized. The complex was characterized by means of elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance, thermogravimetric analysis and central metal titration. The UV and fluorescence spectra were also studied.