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C35.5H31FePdCl2O0.5P2 ({dichloro-[1,1’ -bis (diphenyl) phosphino]-fer-rocene}palladium (Ⅱ) hemi acetone solvate) ,Mr = 760. 74,monoclinic,space group C2/ c,a=33. 993(4),b=10. 424(3),c=18. 364(4) A ,β=104. 52(1)°,V = 6299A3,Z= 8,DC=1.67 g/cm3,μ= 13. 3cm-1,F(000) = 3200,final R= 0.075 for 2058 observed reflections. The environment of the Pd atom is described as a square plane with two cis-chlorine atoms and two phosphorus atoms. The [1, 1’-bisdiphenylphospino] ferrocene (dppf) group is connected to the Pd atom as a bidentate ligand. The Pd-P distances are 2. 278(5) and 2. 278(6) A ;the Pd-Cl distances 2. 323(6) and 2. 345(6) A.
C35.5H31FePdCl2O0.5P2 ({dichloro- [1,1 ’-bis (diphenyl) phosphino] -fer-rocene} palladium (II) hemi acetone solvate), Mr = 760. 74, monoclinic, space group C2 / c, a = 33.993 (4), b = 10.424 (3), c = 18.3644A, β = 104.52 (1) °, V = 6299A3, Z = 8, DC = 1.67 g / cm 3, μ = 13. 3 cm -1, F (000) = 3200, final R = 0.075 for 2058 observed reflections. The environment of the Pd atom is described as a square plane with two cis-chlorine atoms and two phosphorus atoms. The Pd-P distances are 2. 278 (5) and 2. 278 (6) A; the Pd-Cl distances are the same for the Pd atom as a bidentate ligand. [1, 1’-bisdiphenylphospino] 2. 323 (6) and 2. 345 (6) A.