芳烃化合物芳环氯化选择性无论在经济上 ,还是在环境保护上都具有重要意义。本文综述了芳烃化合物包括甲苯、邻二甲苯、卤代苯、氯苄等选择性氯化研究进展 ,介绍了两类主要的催化体系 ,即路易斯酸和含硫助催化剂组成的催化体系及沸石催化体系。指出以沸石分子筛为催化剂进行芳烃化合物芳环选择性氯化是今后研究方向。 Aromatic compounds aromatic chlorination selectivity both in the economy, or in the environmental protection are of great significance. In this paper, the progress of selective chlorination of aromatic compounds including toluene, o-xylene, halobenzene and benzyl chloride is reviewed. Two kinds of major catalytic systems are introduced, namely the catalytic system composed of Lewis acid and sulfur-containing promoter and the zeolite catalyst system. It is pointed out that zeolite molecular sieve as a catalyst for the aromatic ring selective chlorination of aromatic compounds is the future research direction.