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建立了适合于描述溶剂效应的理论线性溶剂化能相关(TLSER)模型。并用该模型对四类异构化反应在不同溶剂下的反应自由能或活化自由能与溶剂的分子结构之间的关系进行了研究,确证了模型的合理性。
A theoretical linear solvatochromatic correlation (TLSER) model suitable for describing solvent effects was established. The model was used to study the relationship between the free energy of activation or the free energy of the four isomerization reactions in different solvents and the molecular structure of the solvent. The rationality of the model was confirmed.