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A novel N,N′-dibenzyl-benzimidazolium tetrachlorocuprate(II) complex, 2, was synthesized and its crystal structure was determined by X-ray diffraction. It crystallizes in monoclinic system, space group P2/c, a=1. 203 9(2) nm, b=0.975 0(2) nm, c=1.878 2(6) nm, β=114.12(2)°, V=2.012 2(8) nm3. Its structure was identified by EA, IR and UV spectra and characterized by elec trochemistry, thermal and magnetic property. The Cu(II) atom of 2- has di storted tetrahedral coordination geometry. In the crystal structure, there are s trong extensive C-H…Cl hydrogen bonds and π-π stacking interactions, which st abilized the crystal structure. CCDC: 221570.
A novel N, N’-dibenzyl-benzimidazolium tetrachlorocuprate (II) complex, 2, was synthesized and its crystal structure was determined by X-ray diffraction. It crystallizes in monoclinic system, space group P2 / c, a = 1.203 9 (2) nm, b = 0.975 0 (2) nm, c = 1.878 2 (6) nm, β = 114.12 (2) ° and V = 2.012 2 (8) nm3. Its structure was identified by EA, IR and UV spectra and characterized by elec trochemistry, thermal and magnetic property. The Cu (II) atom of 2- has di storted tetrahedral coordination geometry. In the crystal structure, there are s trong extensive CH ... Cl hydrogen bonds and π- which st abilized the crystal structure. CCDC: 221570.