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氧气底吹转炉吹炼高钒铁水具有钒氧化率高回收率高,吹炼过程顺行,不喷、不粘、半钢合乎炼钢要求,钒渣V_2O_5品位高,炉衬寿命高等工艺特性且吹钒综合指标良好。它为“含钒钢渣返回高炉富集—火法炼钒铁流程”(简称:单渣返回流程)打通了道路,并给火法提钒提供了一个崭新的工艺方案。 本文阐述了氧气底吹转炉吹钒冶金规律。探讨了钒一碳选择性氧化临界温度的热力学计算,认为按反应产物为FeO·V_2O_3的公式来估算钒一碳选择性氧化临界温度更适合于吹钒实践。选择了适宜的吹炼温度制度及冷却制度。 讨论了动力学条件对脱钒的影响及增碳措施对去钒保碳,提高钒渣质量的效用。
Oxygen bottom blowing converter high vanadium iron with high recovery rate of vanadium oxide high recovery rate, the blowing process on the line, do not spray, non-stick, semi-steel meet the requirements of steel, vanadium slag V_2O_5 high grade, high lining life and process characteristics and blowing Vanadium composite index is good. It opens the way for the “vanadium-bearing steel slag returning to blast furnace enrichment - fire-refining vanadium-iron process” (referred to as the single slag return process), and provides a brand-new process scheme for the vanadium extraction from fire method. This article describes the rule of blowing vanadium metallurgy at oxygen bottom blown converter. The thermodynamic calculation of the critical temperature of selective oxidation of vanadium to carbon is discussed. It is considered that the critical temperature of selective oxidation of vanadium to carbon is more suitable for the practice of blowing vanadium when the reaction product is FeO · V_2O_3. Choose the appropriate blowing temperature system and cooling system. The effect of kinetic conditions on de-vanadium removal and the effect of increasing carbonation on vanadium retention and vanadium slag quality are discussed.