路易斯酸-过渡金属(LA-TM)配合物作为一种新型的双功能催化剂崭露头角.有别于传统的过渡金属双功能催化剂,LA-TM催化剂另辟蹊跷,用路易斯酸功能位点作为电子受体,过渡金属作为电子给体,进行新型的双功能催化.近期,LA-TM配合物迅速发展.依据其键合特点,对硼基LA-TM配合物进行综述,包括sp3杂化、sp2杂化和sp杂化的硼基LA-TM配合物,并归纳了其在LA-TM催化方面的潜在应用,包括H—H/E—H/E—E键活化、氢化、硅氢化和转移脱氢化等等.本综述有望将为开拓LA-TM双功能催化的新领域提供有价值的信息. Lewis acid-transition metal (LA-TM) complexes emerge as a new type of bifunctional catalyst, which is different from the traditional transition metal bifunctional catalysts. LA-TM catalyst is rather strange, with Lewis acid functional sites as electron acceptor Recently, the rapid development of LA-TM complexes.According to its bonding characteristics, the boron-based LA-TM complexes are reviewed, including sp3 hybrid, sp2 hybrid B-based LA-TM complexes were synthesized, and their potential applications in the catalysis of LA-TM were summarized, including H-H / ​​E-H / E-E bond activation, hydrogenation, hydrosilation and translocation Hydrogenation, etc. This review is expected to provide valuable information in developing new fields for the bifunctional catalysis of LA-TM.