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用Raman光谱研究了GeO2PbOZnO玻璃结构,结果表明,这种三元系统红外玻璃主要以[ZnO4]单元和含两个非桥氧的[GeO4]四面体单元共同构成三维网络。网络中含两个非桥氧的[GeO4]四面体数量随PbO含量增加而增加,而低含量的ZnO则能提高网络中[GeO4]四面体单元的聚合度。
The structure of GeO2PbOZnO glass has been investigated by Raman spectroscopy. The results show that the ternary system infrared glass mainly consists of [ZnO4] units and [GeO4] tetrahedron units containing two non-bridging oxygen atoms to form a three-dimensional network. The number of [GeO4] tetrahedra containing two non-bridging oxygen in the network increases with the increase of PbO content, while the low content of ZnO can increase the degree of polymerization of [GeO4] tetrahedron in the network.