【摘 要】
：
标题配合物由高氯酸锌、1,10-二氮杂菲(phen)和苦味酸(HPA)反应而得.其晶体结构通过单晶X-射线衍射法测定,其晶体属三斜晶系,P ī空间群,a = 11.311(2),b = 12.638(4),c = 13
【机 构】
：
广东工业大学轻工化工学院,南京大学配位化学研究所,马来亚大学化学系
论文部分内容阅读
标题配合物由高氯酸锌、1,10-二氮杂菲(phen)和苦味酸(HPA)反应而得.其晶体结构通过单晶X-射线衍射法测定,其晶体属三斜晶系,P ī空间群,a = 11.311(2),b = 12.638(4),c = 13.713(4) (A。）,α = 93.24(3), β = 100.32(2) , γ = 106.50(2)(A。） , Z = 2, V = 1837.1(9)(A。） 3, Dc = 1.660 g/cm3, μ(MoKα) = 0.763 mm-1, F(000) = 936, R = 0.0512, wR = 0.1152.在配合物中, Zn2+离子被2个水分子的2个氧和2个二氮杂菲中的4个氮配位,形成六配位的畸变八面体.苦味酸根作为外界离子以库仑力和氢键与内界离子结合.
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