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由氯甲基化低交联聚苯乙烯和异氰尿酸在三乙胺作用下反应,制得了凝胶型交联聚苯乙烯-异氰尿酸树脂,测定了该树脂对苯酚和间苯二酚在不同温度下的吸附等温线,依据Clapeyron-Clausius方程从吸附等温线计算出了吸附热,从热力学的角度论证了树脂是基于氢键键合和疏水作用而吸附苯酚和间苯二酚的。
By the reaction of chloromethylated low cross-linked polystyrene and isocyanuric acid in the presence of triethylamine, a gel-type cross-linked polystyrene-isocyanurate resin was prepared. The effects of the resin on the hydrolysis of phenol and resorcinol The adsorption isotherms at different temperatures were calculated according to the Clapeyron-Clausius equation from the adsorption isotherms. From the thermodynamic point of view, it was demonstrated that the resins adsorbed phenol and resorcinol on the basis of hydrogen bonding and hydrophobic interaction.