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The title complex, [Cu(phen)_2I][Bi(phen)I_4], has been successfully synthesized by a solution method. Its crystal structure was determined by X-ray diffraction method, and crystallizes in triclinic, space group P1 with a = 10.3876(2), b = 14.4258(5), c = 14.7128(5) ?, α = 82.569(8), β = 73.442(7), γ = 79.299(8)°, V = 2069.68(11) ?3, Z = 2, Dc = 2.323 g/cm3, F(000) = 1318, μ(Mo Kα) = 13.132 mm–1 and T = 293(2) K. The final R = 0.0472 and w R = 0.1147 for 6027 observed reflections with I > 2σ(I). In the structure of the title compound, [Bi(phen)I4]– provides us an opportunity to survey the influence of coordination component on the structure of the cation in the [Cu(phen)2I][Y] system. X-ray diffraction and luminescent spectrum study of the complex are also described.
The title complex, [Cu (phen) 2I] [Bi (phen) I_4], has been synthesized synthesized by a solution method. Its crystal structure was determined by X-ray diffraction method, and crystallizes in triclinic, space group P1 with a = 11.88 (5), α = 82.569 (8), β = 73.442 (7), γ = 79.299 (8) °, V = 2069.68 3, Z = 2, Dc = 2.323 g / cm3, F (000) = 1318, μ (Mo Kα) = 13.132 mm -1 and T = 293 (2) K. The final R = 0.0472 and w R = 0.1147 for 6027 observed reflections with I> 2σ (I). In the structure of the title compound, [Bi (phen) I4] - provides us an opportunity to survey the influence of coordination component on the structure of the cation in the [Cu (phen ) 2I] [Y] system. X-ray diffraction and luminescent spectrum study of the complex are also described.