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本文以氯甲基化聚苯乙烯珠体(简称氯球)为原料,和4-羟基-2.2.6.6-四甲基哌啶氮氧自由基反应,合成出氯球键合氮氧自由基.通过其对醇的氧化反应,考察了负载氮氧自由基的氧化性能.
In this paper, chloromethylated polystyrene beads (referred to as chlorine ball) as raw material, and 4-hydroxy-2.2.6.6-tetramethylpiperidine nitroxide free radical reaction, synthesis of chlorine ball bonded nitrox free base. Through the oxidation of alcohol, the oxidation performance of the supported nitroxides was investigated.