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合成了四-4-(8-喹啉氧基)酞菁铜(Ⅱ)等6种新型酞菁铜衍生物,通过元素分析、红外光谱、顺磁共振、质谱及核磁共振谱加以确认.紫外可见光谱表明它们在氯仿溶液(10~(-5)mol/L)中主要以单分子形式存在,配合物的氯仿溶液在亚相(水)上的π-A曲线表明,它们均有明显的“气-液-固”变化过程,具有良好的形成LB膜性质.
Six novel copper phthalocyanine derivatives, such as copper (Ⅱ) tetrakis 4- (8-quinolinoxy) phthalocyanine, were synthesized and confirmed by elemental analysis, IR, paramagnetic resonance, mass spectrum and nuclear magnetic resonance The visible spectra showed that they exist mainly as single molecules in the chloroform solution (10 ~ (-5) mol / L). The π-A curve of the chloroform solution of the complex in the subphase (water) “Gas - liquid - solid” change process, with the formation of LB film good nature.