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在速率常数的测定中长期存在参数A∞的测量问题,本文拟在介绍一种新方法,该法适用于二级动力学反应,可以提供解决以上问题的可靠方法。对于终点数据无法获得或虽可获得但不可靠时该法特别有用。
In the determination of the rate constant, there exists a long-term measurement problem of the parameter A∞. This article intends to introduce a new method which is suitable for the second-order kinetic reaction and can provide a reliable method for solving the above problems. This method is particularly useful when the end point data is not available or is available but not reliable.