N-羟甲基丙烯酰胺(N-MAM)是一种有重要经济价值的功能高分子单体,其共聚物及交联产物广泛地应用于胶粘剂、涂料、造纸、纺织、土壤改良和塑料改性等领域。我们以树脂为催化剂,水为溶剂合成了高转化率、高纯度的N-MAM,通过合成动力学的研究与NaOH-水体系合成进行了比较,得到了树脂催化优越性的原因。同时考察了N-MAM聚合的影响因素,提出了用红外光谱对共聚组成进行表征的分析方法。实验部分 N-Methylolacrylamide (N-MAM) is a kind of functional polymer with important economic value. Its copolymers and cross-linked products are widely used in adhesives, coatings, papermaking, textile, soil improvement and plastics Sex and other fields. We synthesized a high conversion and high purity N-MAM using resin as catalyst and water as solvent, and compared the synthesis kinetics with NaOH-water system to get the reason of the superiority of resin catalysis. At the same time, the influencing factors of the polymerization of N-MAM were investigated, and the analytical method for characterizing the copolymerization composition by infrared spectroscopy was proposed. Experimental part