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本文研究了Mn(Ⅲ)XPP(PP—原卟啉Ⅸ二甲酯,X—卤素和~-OAc—醋酸根)的共振拉曼光谱和吸收光谱,考察了轴配体的不同对光谱的影响,探讨了吸收光谱各吸收带的性质。对主要的共振拉曼带作了经验归属。
In this paper, the resonance Raman and absorption spectra of Mn (Ⅲ) XPP (PP-protoporphyrin IX dimethyl ester, X-halogen and -OAc-acetate) were investigated. The properties of each absorption band of absorption spectrum were discussed. The main resonance Raman bands have been attributed.