论文部分内容阅读
合成了一系列吡啶N-氧化物-2-甲叉二硫代阱基甲酸酯一价负离子的Cu(Ⅱ)配合物,对其进行了元素分析、红外光谱、电子光谱和室温磁性表征,其中对4个配合物进行了变温磁化率测定和理论拟合,配合物具有二聚体结构单元,其分子内存在铁磁性交换作用,分子间存在反铁磁性交换作用。
A series of Cu (Ⅱ) complexes of pyridinium N-oxide-2-methyldithiophthalate monovalent anions were synthesized and characterized by elemental analysis, IR, electronic spectra and magnetic properties at room temperature. The four complexes were measured and the theoretical fitting was carried out. The complexes have dimer structure units, ferromagnetic exchange in the molecule and antiferromagnetic exchange in the molecule.