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用锌盐、BPP(BPP为1,3-(4-吡啶基)丙烷)、H2ip(H2ip为间苯二酸)反应制得具有金刚石拓扑结构的配位聚合物[Zn(C13H14N2)(C8H4O4)]n.0.5nH2O.利用红外光谱、元素分析、X射线单晶衍射、荧光光谱及热重分析对其进行表征.标题化合物的晶体结构属于单斜晶系,空间群为P 2(1)/n,晶胞参数a=1.104 18(13)nm,b=1.119 24(14)nm,c=1.573 45(18)nm,α=90(°),β=104.150(5)(°),γ=90(°),M r=436.75,V=1.885 5(4)nm3,Z=4,D c=1.539 m g.m-3,F(000)=900,GOF=1.073,R1=0.038 1,ωR2=0.1002.
The coordination polymers [Zn (C13H14N2) (C8H4O4)] with diamond topography were synthesized by the reaction of zinc salt, BPP (BPP is 1,3- (4-pyridyl) propane) and H2ip (isophthalic acid) ] n 0.5 nH 2 O. The crystal structure of the title compound belongs to the monoclinic system with the space group P 2 (1) / n, cell parameters a = 1.104 18 (13) nm, b = 1.119 24 (14) nm, c = 1.573 45 (18) nm, = 90 (°) M r = 436.75 V = 1.885 5 (4) nm3 Z = 4 D c = 1.539 m gm -3 F (000) = 900 GOF = 1.073 R1 = 0.038 1 ωR2 = 0.1002.