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本文研究了Pb2+、Fe(Ⅲ)与H+在氯盐溶液中在石墨阴极与铅阴极上的还原。在石墨阴极上,H+、Fe(Ⅲ)与Pb2+共同还原是难以避免的,而在铅阴极上则可避免H+的同时还原,可获得更高的铅沉积的电流效率。
In this paper, the reduction of Pb2 +, Fe (Ⅲ) and H + on graphite cathode and lead cathode in a chloride salt solution was studied. On the graphite cathode, the common reduction of H +, Fe (Ⅲ) and Pb2 + is unavoidable, while simultaneous reduction of H + can be avoided on the lead cathode, which leads to higher current efficiency of lead deposition.