近来,关于氯离子选择性电极的报导甚多,其中大都用氯化银——硫化银压片制成膜电极。也有使用氯化银——硅酮橡胶的不均态压片薄膜电极、银——氯化银极化膜电极,氯化银单晶膜电极、液体离子交换膜电极和微型电极。这些电极曾用于矿物岩石、水、浸取液、磷酸钙、电解液和气体中氯的测定。我们用克分子比为1∶1的氯化银——硫化银混合物制成均态固体薄膜氯离子选择性电极,测定了它 Recently, there have been many reports on chloride ion selective electrodes, most of which were made into film electrodes by silver chloride-silver sulfide tablets. There are also non-uniform pressing film electrode using silver chloride-silicone rubber, silver-silver chloride polarizing film electrode, silver chloride single crystal film electrode, liquid ion exchange membrane electrode and microelectrode. These electrodes were used for the determination of chlorine in mineral rocks, water, leachate, calcium phosphates, electrolytes and gases. We use a silver chloride - silver sulfide mixture at a molar ratio of 1: 1 to form a homogeneous solid film chloride ion selective electrode. It was determined that it