用2-氨基-5-巯基-1,3,4-噻二唑乙酸(Hatma)为配体合成出一种金属锌配合物[Zn(atma)2]n,其结构通过IR、TGA、元素分析和X-射线单晶衍射法确定。从结构中看出,配合物通过π-π作用、分子间氢键作用和基团间的嵌合作用,由二维层状结构自组装形成一个三维的超分子骨架。电化学研究表明配合物中的Zn2+/Zn+对的氧化还原是一个不可逆过程。抗菌试验表明,该配合物比配体表现出更好的生物活性。 A metal zinc complex [Zn (atma) 2] n was synthesized by using 2-amino-5-mercapto-1,3,4-thiadiazoleacetic acid as a ligand. The structure was characterized by IR, TGA, Analysis and X-ray single crystal diffraction method. It can be seen from the structure that the complex is self-assembled by two-dimensional layered structure to form a three-dimensional supramolecular framework through π-π interaction, intermolecular hydrogen bonding and intermolecular chimerism. Electrochemical studies show that the complex of Zn2 + / Zn + redox is an irreversible process. Antibacterial tests showed that the complex showed better biological activity than the ligand.