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利用循环伏安法研究了膦硫混配原子簇化合物Co_6S_8[P(OCH_3)_3]_6的电化学行为,结果表明Co_6S_8[P(OCH_3)_3]_6在CH_2Cl_2溶液中可现察到三个可逆氧化还原过程,其电子转移过程为:并探讨了其电子转移的机理和结构构型的关系以及作为电子贮存分子器件的可能性.
The electrochemical behavior of Co_6S_8 [P (OCH_3) _3] _6 was investigated by cyclic voltammetry. The results showed that three reversible reactions of Co_6S_8 [P (OCH_3) _3] _6 in CH_2Cl_2 solution were observed The redox process, the electron transfer process is: and discusses the mechanism of its electron transfer and the relationship between the structural configuration as well as the possibility of electronic storage molecular devices.