【摘 要】
：
本文利用刚性三叉酸配体H3tatb(4,4,4"-(1,3,5-三嗪-2,4,6-三基)三苯甲酸)与过渡金属Cu(Ⅱ)离子以及辅助配体邻菲罗啉在水热条件下进行自组装,得到了一种过渡金属有机配
【机 构】
：
中国石油大学(北京)理学院,北京,102249
论文部分内容阅读
本文利用刚性三叉酸配体H3tatb(4,4,4"-(1,3,5-三嗪-2,4,6-三基)三苯甲酸)与过渡金属Cu(Ⅱ)离子以及辅助配体邻菲罗啉在水热条件下进行自组装,得到了一种过渡金属有机配合物[Cu(tatb)2(phen)],通过X-射线单晶衍射结构分析得到一个零维结构。该化合物属于正交晶系,Pcca空间群。不对称单元中包含一个Cu离子,两个H3tatb羧酸配体分子,一个邻菲罗啉分子。该零维结构通过氢键连接成一维链,通过一维链组成一个紧密的二维层。层与层之间通过π…π作用堆积成一个三维的超分子结构。此外,研究了这种化合物的热稳定性能和磁性。
其他文献
In the past decades,copper complexes of pyrazolate ligands have been extensively studied due to their structural chemistry and their potential applications
本文利用刚性三叉酸配体H3tatb(4,4',4"-(1,3,5-三嗪-2,4,6-三基)三苯甲酸)与过渡金属离子Zn以及辅助配体2,2'-联吡啶进行自组装,得到了一种过渡金属有机配合物[Zn3(tatb
The crystal engineering of metal-organic frameworks(MOFs)has grown into a subject that attracts intense attention because controlling the molecular organiza
Metal-organic coordination polymers,which constructed from metal ions and multifunctional organic ligands,as an important class of solid-state materials hav
A new complex Pb(bmzbc)2 with 4-(benzmidazole-1-yl)benzoate(bmzbc)ligand has been synthesized by hydrothermal reaction.
A new silver compound of [Ag2(μ2-pip)(Hpip)2](BPDSDC)·10(H2O)(1)(H4BPDSDC = biphenyl-3,3'-disulfonyl-4,4'-dicarboxylic acid,pip = piperazine)has been synt
A novel metal-organic coordination compound,[Zn(μ2-OH)(ATZ)]n(ATZ = 5-amino-1H-tetrazole),has been synthesized through hydrothermal reaction using 5-amino-
A 1D dysprosium-carboxylate coordination polymer,[Dy4(μ3-OH)4(L)8]n(1)(HL = 2-(3-chlorophenoxy)propionic acid),has been synthesized and crystal structural
Two 3D coordination polymers,[Tb3(BDC)4.5(H2O)(DMF)2]n(1)and [Tb2(BDC)3(H2O)2(DMF)2]n(2)(H2BDC=1,4-benzenedicarboxylic acid),have been synthesized and struc
本文利用2,2,2"-(((2,4,6-三甲基苯-1,3,5-三基)三(亚甲基))三(硫基))苯三甲酸配体和Na(NO3)进行自组装,合成了二维的金属—有机框架化合物。通过X-射线单晶衍射结构分析