【摘 要】
：
以FeSO4和二吡啶[3,2-a:2’,3’-c]并吩嗪(DPPZ)为原料,采用水热法合成了一维链状配位聚合物{[Fe(SO4)(DPPZ)2].H2O}n,利用元素分析、红外光谱、X射线单晶衍射和热重分析对其
【机 构】
：
江苏大学化学与化工学院,吉林师范大学化学学院,
论文部分内容阅读
以FeSO4和二吡啶[3,2-a:2’,3’-c]并吩嗪(DPPZ)为原料,采用水热法合成了一维链状配位聚合物{[Fe(SO4)(DPPZ)2].H2O}n,利用元素分析、红外光谱、X射线单晶衍射和热重分析对其结构进行了表征。该配合物属于单斜晶系,P21/m空间群,a=1.3569(3)nm,b=0.6519(13)nm,c=1.7250(3)nm,α=90°,β=111.29(3)°,γ=90°,V=1.4217(5)nm3,Z=2,dc=1.713g/cm3,μ=0.671mm-1,F(000)=750,R1=0.0491,wR2=0.1250。
One-dimensional chain-like coordination polymer {[Fe (SO4) (Fe (SO4))] was synthesized by the hydrothermal method using FeSO4 and dipyridyl [3,2-a: 2 ’, 3’-c] DPPZ) 2] .H2O} n. Its structure was characterized by elemental analysis, IR, single crystal X-ray diffraction and thermogravimetric analysis. The complex belongs to the monoclinic space group, a = 1.3569 (3) nm, b = 0.6519 (13) nm, c = 1.7250 (3) nm, α = 90 ° and β = 111.29 (3) °, γ = 90 °, V = 1.4217 (5) nm3, Z = 2, dc = 1.713 g / cm3, μ = 0.671 mm-1, F (000) = 750, R1 = 0.0491, wR2 = 0.1250.
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