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利用研制的紫外-可见多功能光谱电化学池,以UV-Vis 长光程薄层和光透薄层光谱电化学法分别测定了Fe(CN)63- /Fe(CN)64- 电对的反应电子数n;并以UV-Vis 光透半无限扩散和平行入射式光谱电化学法分别测定了Fe(CN)63- 的扩散系数D。实验的结果均与文献值相近,从而表明了这种UV-Vis多功能光谱电化学池的可靠性。
The reaction of Fe (CN) 63- / Fe (CN) 64-pair was measured by UV-Vis long-path optical thin-film and optical thin-film spectrophotometry using developed UV- Electron number n; and the diffusivity D of Fe (CN) 63- was measured respectively by UV-Vis optical semi-infinite diffusion and parallel incident-spectrum electrochemical method. The experimental results are similar to the literature values, thus demonstrating the reliability of this UV-Vis multifunctional spectral electrochemical cell.