【摘 要】
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The title complex [Cu2(bipy)2·Oac·Cl·OH]·TsTausH·3H2O(C31H37ClCu2N5O11S2) has been synthesized by the reaction of 2,2-bipyridine(bipy), N-P-tolysulfony tau
【机 构】
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Department of Chemistry and Chemical Engineering,Department of Material and Chemical Engineering
论文部分内容阅读
The title complex [Cu2(bipy)2·Oac·Cl·OH]·TsTausH·3H2O(C31H37ClCu2N5O11S2) has been synthesized by the reaction of 2,2-bipyridine(bipy), N-P-tolysulfony taurine (TsTausH) and copper acetate in water-ethanol solution, and its crystal structure was determined by X-ray diffraction method. The crystal belongs to triclinic, space group Pī with a = 0.74485(14), b = 1.6094(3), c = 1.7472(3) nm, α = 114.662(4), β = 99.997(4), γ = 93.218(4)o, V = 1.8551(6) nm3, Mr = 882.31, Z = 2, Dc = 1.580 g/cm3, μ= 1.395 mm-1 and F(000) = 906. The complex is a binuclear copper compound, and the two copper ions nearly have the same coordination environment. There exists M-M bond in the complex. The distance of Cu(1)-Cu(2) is 0.29747(7) nm. The two ions form two distorted octahedral geometries.
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