论文部分内容阅读
研究了二氯二苯基锡（Ｐｈ＿２ＳｎＣｌ＿２）与核酸的基本组成单元──单核苷酸在水相中的配位作用，并用热分析、傅利叶变换红外光谱和￣１Ｈ、￣（３１）Ｐ超导核磁共振谱对新配合物Ｐｈ＿２Ｓｎ（５＇－ＡＭＰ）·Ｈ＿２Ｏ、Ｐｈ＿２Ｓｎ（５＇－ＣＭＰ）·Ｈ＿２Ｏ和Ｐｈ＿２Ｓｎ（５＇－ＧＭＰ）进行了详细的表征。结果表明，在配合物中锡仅与单核苷酸的磷酸根结合，给出了配合物的可能结构。
The basic unit of dichloro-diphenyltin (Ph_2SnCl_2) and nucleic acid was studied. The coordination of mononucleotide in aqueous phase was investigated by thermal analysis, Fourier transform infrared spectroscopy and Fourier transform infrared spectroscopy The new complexes Ph_2Sn (5’-AMP) · H_2O, Ph_2Sn (5’-CMP) · H_2O and Ph_2Sn (5’-GMP) were characterized by nuclear magnetic resonance spectroscopy. The results show that in the complex tin only with single nucleotide phosphate, given the possible structure of the complex.