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利用卤素置换反应合成了4种含杂环的二茂铁亚胺碘桥键异环环钯化合物2及4种碘代含杂环的二茂铁亚胺异环环钯化合物3,其中化合物3的结构经元素分析、1H NMR及IR确证,3a用X射线单晶衍射测定了晶体结构。这些化合物在空气中稳定。
Four kinds of heterocyclic ferrocene iodine bridged isocyclic palladium compounds 2 and four kinds of iodinated heterocyclic ferrocenylimino ring compounds 3 were synthesized by halogen exchange reaction. Among them, compound 3 The structure was confirmed by 1H NMR and IR. The crystal structure was determined by X-ray single crystal diffraction. These compounds are stable in the air.