Synthesis and Crystal Structure of Dinuclear Copper Complex [Cu(CH_2O(C_6H_4)N=C(C_6H_4)O)(Py)]_2

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The complex [Cu2L2(Py)2] (H2L=2-aminobenzoic alcohol condensation salicylaldehyde) was obtained. A single-crystal X-ray study shows that the complex is a binuclear compound (Cu2C38H32N4O4). The coordination geometry about each copper atom is best described as a distorted square pyramid. The compound [Cu2L2(Py)2] belongs to monoclinic system with space group P21, lattice constants: a = 10.3881(1), b = 17.9724(1), c = 17.5800(2) ? b =90.4880(1), V= 3282.05(5) 3, Z= 4, Mr =735.75, Dc=1.489 g/cm3, m= 1.344mm-1, F(000) = 1512, R=0.0519, wR=0.1092 for 6725 reflections with I >2s(I). The distances between Cu(II) and O atoms are range from 1.898(6) to1.976(5)? between Cu(II) and N atoms are range from 1.990(6) to 2.369(7)? The Cu(1)Cu(2) bond length is 3.024(4) ? The complex [Cu2L2 (Py) 2] (H2L = 2-aminobenzoic alcohol condensation salicylaldehyde) was obtained. A single-crystal X-ray study shows that the complex is a binuclear compound (Cu2C38H32N4O4). The coordination geometry about each copper atom is The compound [Cu2L2 (Py) 2] belongs to monoclinic system with space group P21, lattice constants: a = 10.3881 (1), b = 17.9724 (1), c = 17.5800 (2)? best described as a distorted square pyramid. m = 1.344 mm-1, F (000) = 1512, R = 0.0519, wR = 0.1092 for 6725 reflections with I> 2s (I). The distances between Cu (II) and O atoms are range from 1.898 (6) to 1.976 ) to 2.369 (7)? The Cu (1) Cu (2) bond length is 3.024 (4)?
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