本文结合我们实验室所开展的一些工作,对多工作电极流动薄层电化学检测器及其电解色谱的一些新进展作了评述。着重介绍了三种结构类型即串联型、并联型和对向并列型的双工作电极检测器的设计和用途。本文还就双工作电极薄层电化学检测器与液相色谱结合的基本原理、优点和一些应用进行了讨论。最后简要地介绍了电解色谱的基本原理、进展及应用近况。 In this paper, some work carried out in our laboratory is reviewed, and some new developments of multi-working electrode flow thin-layer electrochemical detector and its electrolysis chromatography are reviewed. The design and application of three kinds of double-working electrode detectors of tandem type, parallel type and opposite-side parallel type are mainly introduced. This paper also discussed the basic principle, advantages and some applications of double working electrode thin-layer electrochemical detector and liquid chromatography. Finally, the basic principle, progress and application of electrolytic chromatography are briefly introduced.