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1930年鲁夫(Ruff)和克鲁克(Krug)首先用元素氟与氯直接化合制成了三氟化氯,并且报导过它的一些性质。当时,元素氟未能大规模生产,三氟化氯又被认为是一个反应极难控制的化合物,所以直到第二次世界大战前夕,没有进一步研究它。战时德国开始了元素氟的较大规模的生产,曾经生产三氟化氯作为枞火剂。战后一些国家先后进行三氟化氯的生产,学者们相继系统地研究了它的物理性质,阐明了它的分子结构,并且逐渐找到了控制其反应的方法,在无机物制备和有机合成上有了新的应用。三氟化氯是化学活性最强的一种卤素氟化合物,
In 1930 Ruff and Krug first made the chlorine trifluoride by direct combination of elemental fluorine with chlorine and reported on some of its properties. At the time, elemental fluorine was not produced on a large scale and chlorine trifluoride was also considered to be a very refractory compound, so it was not studied further until the eve of World War II. Wartime Germany began the larger-scale production of elemental fluorine, which once produced chlorine trifluoride as a firming agent. After the war, some countries successively carried out the production of chlorine trifluoride. Scholars have systematically studied its physical properties, elucidated its molecular structure, and gradually found a way to control its reaction in the preparation of inorganic and organic synthesis With new applications. Chlorine trifluoride is one of the most chemically active halogen fluorine compounds,