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合成了一种新型的导电配位型化合物(FeCp2)0.65[Ni(C3S7)2]。通过EA,ICP,1H NMR,UV对该化合物进行了表征,并通过循环伏安法和变温四探针法对其电化学性质进行了研究。结果表明分子中S原子个数增多以及二茂铁阳离子(FeCp2+)的引入有利于导电性能的提高。
A novel conductive coordination compound (FeCp2) 0.65 [Ni (C3S7) 2] was synthesized. The compounds were characterized by EA, ICP, 1H NMR and UV. The electrochemical properties of the compounds were studied by cyclic voltammetry and four temperature probe. The results show that the number of S atoms in the molecule is increased and the introduction of ferrocene cation (FeCp2 +) is conducive to the improvement of the conductivity.