论文部分内容阅读
The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)2(NO3)]··0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3 064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.033 2, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.
The bismuth complex with dithiopiperdylcarbamate [Bi (S2CNC5H10) 2 (NO3)] · 0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2 / c, a = 3.140 (2) nm, b = 1.176 4 (9) nm, c = 2.021 6 (15) nm, β = 103.081 (12) °, V = 5.713 3 064, Dc = 1.815 g · cm -3, μ = 6.502 mm -1. The final R1 = 0.033 2, wR2 = 0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.