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A new nickl(Ⅱ) complex containing the thiazole-substituted nitroxide radical with the formula Ni(NIT2-thz) 2Cl 2(NIT2-thz=4,4,5,5-tetramethyl-2-(2′-thiazole)imidazolin-1-oxyl-3-oxide) was synthesized and its crystal structure was determined. The magnetic property analysis indicates that there is strong antiferromagnetic interactions between Ni(Ⅱ) and radical(J=-71.82 cm -1).
A new nickl (II) complex containing the thiazole-substituted nitroxide radical with the formula Ni (NIT2-thz) 2Cl2 (NIT2-thz = 4,4,5,5-tetramethyl-2- (2’-thiazole) imidazolin- The magnetic property analysis indicates that there is strong antiferromagnetic interactions between Ni (Ⅱ) and radical (J = -71.82 cm -1).