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在研究Ｏ，Ｏ二烷基Ｏ芳基硫代磷酸酯（１）与三氯氧磷的异构化氯化反应机理时，发现１的异构化产物Ｏ，Ｓ二烷基硫代磷酸酯（４）能顺利地与三氯氧磷反应，４中的烷氧基被氯原子取代，得到的产物Ｓ烷基硫代磷酰氯酯（２）和Ｏ烷基磷酰二氯酯３．当４中的Ｒ为烷基或苯基，Ｒ’为烷氧基、芳氧基、烷硫基、芳硫基、二烷基氨基、氮杂环基、苯基和甲基，Ｒ”为Ｃ１—４烷基时，４的氯化反应也能顺利发生，并得到较高产率的预期产物
In the study of O, O dialkyl O aryl phosphorothioate (1) and phosphorus oxychloride isomerization chlorination reaction mechanism, we found that 1 isomerization products O, S dialkyl sulfides The phosphorothioate (4) can be smoothly reacted with phosphorus oxychloride, the alkoxy group of 4 is replaced by a chlorine atom, and the obtained product S-alkyl thiophosphoryl chloride (2) and O-alkyl phosphoryl di Chloride 3. When R4 is alkyl or phenyl, R ’is alkoxy, aryloxy, alkylthio, arylthio, dialkylamino, azacyclic, phenyl and methyl, R "is C1-4 alkyl, the 4 chlorination reaction can be smoothly, and to obtain a higher yield of the desired product